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PMID: 16592270 Published · ppublish English Journal Article

The triplet state in bacterial photosynthesis: Possible mechanisms of the primary photo-act.

Thurnauer MC, Katz JJ, Norris JR

Abstract

In vitro and in vivo triplet state electron paramagnetic resonance (epr) spectra of bacteriochlorophylls (Bchls) show important differences in (a) electron spin polarization (esp), and (b) zero field splitting (ZFS) parameters. The unusual esp and ZFS properties of the observed in vivo triplet state are best interpreted as arising from a short-lived radical pair precursor (not directly observable by epr) formed in or with the special pair of bacteriochlorophyll molecules involved in the primary photo-act.

Authors & Affiliations
3 authors, click to expand affiliations / ORCID
Thurnauer M C
Chemistry Division, Argonne National Laboratory, Argonne, Illinois, 60439.
Katz J J
Norris J R
References (14)
14 references, click to expand
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Article Info
Journal
Proceedings of the National Academy of Sciences of the United States of America
Abbr.
Proc Natl Acad Sci U S A
ISSN
0027-8424
Published
1975-09-00
Pages
3270-4
Language
English
Region
United States
NLM ID
7505876
PMCID
PMC432970
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