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PMID: 17284026 Published · ppublish English Journal Article Research Support, N.I.H., Extramural

Photochemical production of a highly reactive porphyrin-iron-oxo species.

Inorganic chemistry ·Vol. 46 ·No. 5 ·2007-03-05 ·Pages 1517-9

Pan Z, Zhang R, Fung LW, Newcomb M

Abstract

Oxidation of 5,10,15,20-tetramesitylporphyrinatoiron(III) perchlorate, (TMP)FeIII(ClO4), with ferric perchlorate in acetonitrile gave a metastable species identified as (TMP)FeIV(ClO4)2 that decayed within seconds to the known isomeric species (TMP*+)FeIII(ClO4)2. Irradiation of the metastable species with 355 nm laser light gave a highly reactive transient that reacts with simple organic reductants (alkenes and arylalkanes) 5 orders of magnitude faster than known Compound I analogues, (TMP*+)FeIV(O)(X-).

MeSH Terms
Iron/chemistry,radiation effects Metalloporphyrins/chemical synthesis,chemistry,radiation effects Molecular Structure Photochemistry Porphyrins/chemistry,radiation effects Ultraviolet Rays
Chemicals
Metalloporphyrins Porphyrins Iron
Authors & Affiliations
4 authors, click to expand affiliations / ORCID
Pan Zhengzheng
Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607, USA.
Zhang Rui
Fung Leslie W-M
Newcomb Martin
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Article Info
Journal
Inorganic chemistry
Abbr.
Inorg Chem
ISSN
0020-1669
DOI
10.1021/ic061972w
Published
2007-03-05
Epub
2007-00-07
Pages
1517-9
Language
English
Region
United States
NLM ID
0366543
PMCID
PMC2525790
Subset
IM
Grants
NIGMS NIH HHS · GM-068621 · United States
NIGMS NIH HHS · R01 GM068621-05 · United States
NIGMS NIH HHS · GM-48722 · United States
NIGMS NIH HHS · R01 GM048722-14 · United States
NIGMS NIH HHS · R01 GM068621 · United States
NIGMS NIH HHS · R01 GM048722 · United States
External Links
PubMed source DOI: 10.1021/ic061972w PMC Full Text View journal details
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