Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(II) coordination.

Chemical communications (Cambridge, England) ·Vol. 52 ·No. 29 ·2016-08-19

Zhang Kai, Savage Mathew, Li Xin, Jiang Yu, Ishida Masatoshi, Mitsuno Koki, Karasawa Satoru, Kato Tatsuhisa, Zhu Weihua, Yang Sihai, Furuta Hiroyuki, Xie Yongshu

Abstract

A rational and effective approach for synthesizing linear π-conjugated hexa-, hepta- and octapyrrins through the regioselective oxidative coupling of monoacylated tripyrrane and bilane is described. Depending upon the numbers of pyrrolic units, the geometry and properties of bis-copper(II) complexes could be systematically modulated.

Article Info

Journal

Chemical communications (Cambridge, England)

Abbr.

Chem Commun (Camb)

ISSN

1359-7345

DOI

10.1039/c6cc00707d

Published

2016-08-19

Indexed

2016-03-31

Updated

2016-03-31

Language

English

Country/Region

England

NLM ID

9610838

External Links

PubMed source DOI: 10.1039/c6cc00707d View journal details

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Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(II) coordination.

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