Synthesis and crystal structure of LaCr Al Ge C [ = 0.22 (2) and = 0.758 (19)].

Single crystals of a new multinary chromium carbide, LaCr Al Ge C (henicosa-lanthanum octa-chromium aluminium hexa-germanium dodeca-carbide), were grown from an La-rich self flux and were characterized by single-crystal X-ray diffraction. The face-centered cubic crystal structure is composed of isolated and geometrically frustrated regular Cr tetra-hedra that are co-centered within regular C octa-hedra. These mutually separated CrC clusters are distributed throughout a three-dimensional framework of Al, Ge, and La. The title compound is isotypic with LaMnC and FeC ( = La, Ce, Pr; = Al, Bi, Ge, Sn, Sb, Te) and represents the first example of a Cr-based compound with this structure-type.