Abstract
Characterizing the biological effects of metabolic transformations (or biotransformation) is one of the key steps in developing safe and effective pharmaceuticals. Sulfate conjugation, one of the major phase II biotransformations, is the focus of this study. While this biotransformation typically facilitates excretion of metabolites by making the compounds more water soluble, sulfation may also lead to bioactivation, producing carcinogenic products. The end result, excretion or bioactivation, depends on the structural features of the sulfation sites, so obtaining the structure of the sulfated metabolites is critically important. We describe herein a very simple, high-throughput procedure for using mass spectrometry to identify the structure-and thus the biological fate-of sulfated metabolites. We have chemically synthesized and analyzed libraries of compounds representing all the biologically relevant types of sulfation products, and using the mass spectral data, the structural features present in these analytes can be reliably determined, with a 97% success rate. This work represents the first example of a high-throughput analysis that can identify the structure of sulfated metabolites and predict their biological effects.
MeSH Terms
Alcohols/chemistry,metabolism
Chemistry, Pharmaceutical/methods
Hydroxylamines/chemistry,metabolism
Metabolic Detoxication, Phase II
Molecular Structure
Pharmaceutical Preparations/metabolism
Spectrometry, Mass, Secondary Ion
Structure-Activity Relationship
Sulfates/analysis,chemistry,metabolism
Chemicals
Alcohols
Hydroxylamines
Pharmaceutical Preparations
Sulfates
Authors & Affiliations
5 authors, click to expand affiliations / ORCID
Yi Lin
Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS 66045, USA.
Dratter Joe
Wang Chao
Tunge Jon A
Desaire Heather
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